Part II · Chapter 9

Pure vs. Mixed States

Read ~16 min Prerequisites Ch. 3, Ch. 8 Tools purity disc, code cell Live
Basic

Ch. 3's Bloch sphere only ever showed you the surface. That wasn't a simplification for beginners — it was the surface specifically because every state on it was pure. Density matrices unlock the rest of the ball.

The purity test

One number tells you everything: Tr(ρ²).

  • Tr(ρ²) = 1 → pure state. Sits exactly on the Bloch sphere's surface.
  • Tr(ρ²) < 1 → mixed state. Sits somewhere inside the ball — the smaller Tr(ρ²) gets, the closer to dead center.
  • Tr(ρ²) = 1/2 (the minimum, for a qubit) → the maximally mixed state, I/2, sitting exactly at the center. No direction is preferred at all — it's the quantum equivalent of a fair, unbiased coin.
Fig. 9.1 — drag the point anywhere inside the discTr(ρ²) live
This is the exact same θ-angle picture from Ch. 3's Fig. 3.1 — now generalized so the point can sit anywhere inside the disc, not just on the boundary. Drag straight to the center: that's I/2.
Intermediate

Superposition is not the same thing as a mixture

This is the single most common mix-up at this stage, so it's worth stating bluntly: |+⟩ = (|0⟩+|1⟩)/√2 is a pure state — it sits right on the equator, Tr(ρ²)=1. A 50/50 classical mixture of |0⟩ and |1⟩ is a genuinely different, mixed state — I/2, dead center, Tr(ρ²)=0.5. Both "give 50/50 outcomes when measured in the Z basis," which is exactly why it's tempting to conflate them. But measure in the X basis and the difference is obvious: |+⟩ gives a certain "+" outcome every time (Ch. 7), while I/2 gives 50/50 no matter which basis you measure in. Superposition is coherent and basis-dependent; a mixture is incoherent classical uncertainty, the same in every basis.

Advanced

Why Tr(ρ²) is the right quantity (not just a convenient one)

Writing ρ in terms of the Bloch vector r = (rₓ,r_y,r_z), with |r| ≤ 1, gives the clean closed form Tr(ρ²) = (1+|r|²)/2 — which is exactly what Fig. 9.1 computes as you drag. This isn't a coincidence of notation: Tr(ρ²) is one specific case of a whole family of quantities called Rényi entropies that measure "how mixed" a state is, and it has a special practical virtue over alternatives like von Neumann entropy (Ch. 15): it's just a trace of a matrix product, with no logarithm and no eigendecomposition required, which is why it's usually the first thing people check.

Fig. 9.2 — code, runs in your browser
⟨X⟩ = 1 for |+⟩ but ⟨X⟩ = 0 for I/2 — the exact numerical version of the "not the same thing" claim above.
Check your understanding

What value of Tr(ρ²) signals a pure state, and what value signals the maximally mixed qubit state?

1 for pure; 0.5 for maximally mixed (the minimum possible for a single qubit).

Check your understanding

|+⟩ and I/2 both give 50/50 outcomes when measured in the Z basis. How do you tell them apart?

Measure in the X basis instead. |+⟩ gives a certain "+" outcome every time; I/2 still gives 50/50, since it has no preferred direction in any basis.

Check your understanding

Where does a mixed state sit relative to the Bloch sphere's surface?

Strictly inside it — the lower the purity, the closer to the exact center, which is the maximally mixed state I/2.

Check your understanding

If |r| = 0.6 for some qubit's Bloch vector, what is Tr(ρ²)?

(1 + 0.36)/2 = 0.68 — using Tr(ρ²) = (1+|r|²)/2.

Check your understanding

In one sentence, what's the conceptual difference between superposition and a classical mixture?

Superposition is coherent and basis-dependent — a specific pure state with a definite outcome in some basis; a mixture is incoherent classical uncertainty about which state you actually have, equally "spread out" in every basis.

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